RT Journal Article T1 Geochemical evolution and elemental behaviour of playa sediments: impacts of natural weathering and agricultural practices A1 Halmos, Laszlo A1 Delgado-Rodríguez, Joaquín A1 Rodríguez, Miguel A1 Rodríguez-Rodríguez, Miguel A1 Jiménez Bonilla, Alejandro A1 Díaz Azpiroz, Manuel K1 Lagunas tipo playa K1 Alcalino K1 Degradación ecológica K1 Meteorización química K1 Índice de fraccionamiento (FI) K1 Estrategias de conservación AB Playas are predominantly alkaline wetlands common in arid and semi-arid regions. These unique ecosystems are heavily influenced by climatic and hydrological processes, such as high evapotranspiration rates and negative water balance. Numerous studies have documented the ecological degradation of these saline ecosystems due to both anthropogenic and natural processes. The present research analyses the mineralogical and elemental changes in six representative playas at different degradation stages in the western External Betics. Chemical weathering and element fractionation were examined to identify the key geochemical factors involved in the degradation of these playa wetlands. A novel methodology for calculating the Fractionation Index (FI) has been developed and applied alongside established geochemical indices, such as the Chemical Index of Alteration (CIA), Chemical Index of Weathering (CIW), and Vogt’s Residual Index (VRI), as well as analyses of elemental distribution. This approach allows for a comprehensive differentiation of the geochemical processes occurring in nonsaline-alkali, saline-alkali, and degraded playas. The study highlights the role of alkalinity in promoting clay mineral formation, with Na+ and Ca2+ dominating the cationic composition. These findings provide insights into the dynamics of playa ecosystems and inform conservation strategies for managing these vulnerable environments. PB Springer Nature YR 2025 FD 2025-09-15 LK https://hdl.handle.net/10433/26291 UL https://hdl.handle.net/10433/26291 LA en NO Journal of Iberian Geology vol 51, p. 495–515 NO Proyectos de investigaciónPID2024-159481NB-I00 NO Universidad Pablo de Olavide. Departamento de Sistemas Físicos, Químicos y Naturales DS RIO RD May 9, 2026