RT Journal Article T1 Evaluation of the olive mill wastewater treatment based on advanced oxidation processes (AOPs), flocculation, and filtration A1 Agabo-García, Cristina A1 Repetto, Guillermo A1 Albqmi, Mha A1 Hodaifa, Gassan K1 AOPs K1 Photo-Fenton K1 Flocculation-sedimentation K1 FiltrationToxicity AB Different eco-friendly processes are under study to treat olive mill wastewater in the line with European 2024 zero-waste plan. This study is focused on the application of advanced oxidation processes, flocculation, and filtration to determine the best operational condition to obtain high-quality regenerated water in a simple and fast process. In this sense, after photo-Fenton high organic matter removal percentages were obtained: turbidity = 78.3 ± 6.4 %, chemical oxygen demand = 82.9 ± 0.1 %, total organic carbon = 68.9 ± 8.2 %, total phenolic compound = 20.8 ± 9.1 %, and total nitrogen = 64.1 ± 2.1 %. However, the total iron was increased to 792 ± 71 mg/L generating toxicity in the wastewater (100 % mortality in D. magna toxicity test). The subsequent flocculation and filtration steps, refine the water quality. In this sense, different flocculants have been studied to optimize regenerated treated water and the operations time, determining the sedimentation rate in a typical Kynch curve. In quality terms, adjusting the oxidized water to pH = 6 showed the best option to determine lowest values of COD = 131 mg O2/L, TPCs = 0.110 mg/L, and total iron = 0.380 mg/L but with high values for sodium = 1320 mg/L and chloride ions = 473 mg/L. However, with a minimum amount of Nalco 9913 (10 mg/L) and Nalco GR-204 (50 mg/L) highest sedimentation rate was achieved. After three filtration steps, regenerated water for irrigation purposes with the following quality parameters pH = 7.0, electric conductivity = 6.04 mS/cm, turbidity = 0.66 FTU, COD = 451 mg O2/L, TOC = 142 mg/L, TPCs = 0.13 mg/L; sodium ions = 1.50 mg/L, chloride ions = 221 mg/L, total iron = 0.247 mg/L, and no toxicity was obtained. PB Elsevier YR 2023 FD 2023 LK https://hdl.handle.net/10433/19534 UL https://hdl.handle.net/10433/19534 LA en NO Journal of Environmental Chemical Engineering Volume 11, Issue 3, June 2023, 109789 NO The Junta of Andalusia and Ministry of Economy and Competitiveness (Spain) are acknowledged for financial support through Project Ref.: AGR-7092 “Application of advanced oxidation technologies for treating of washing wastewaters of olive oil and olives”. Authors also thank the University of Pablo de Olavide for its “Financing of the Bridge Projects” charged to the Strengthening Plan for R+D+i funded by the Ministry of Economy and Knowledge of the Junta of Andalucía, Ref.: CTM2016-78950-C2-1-R. Funding for open access publishing: Universidad Pablo de Olavide/CBUA. NO Universidad Pablo de Olavide. Departamento de Biología Molecular e Ingeniería Bioquímica DS RIO RD May 22, 2026