RT Journal Article
T1 Influence of Redox Couple on the Performance of ZnO Dye Solar Cells and Minimodules with Benzothiadiazole-Based Photosensitizers
A1 Gonzalez-Flores, Carlos A.
A1 Pourjafari, Dena
A1 Escalante, Renan
A1 Canto-Aguilar, Esdras J.
A1 Vega Poot, Alberto
A1 Andres Castán, José Maria
A1 Kervella, Yann
A1 Demadrille, Renaud
A1 Riquelme Expósito, Antonio Jesús
A1 Anta, Juan
A1 Oskam, Gerko
K1 Microwave-assisted solvothermal synthesis
K1 Photoelectrochemistry
K1 Organic dyes
K1 Recombination impedance
K1 Solar minimodules.
AB ZnO-based dye-sensitized solar cells exhibit lower efficiencies than TiO2-based systems despite advantageous charge transport dynamics and versatility in terms of synthesis methods, which can be primarily ascribed to compatibility issues of ZnO with the dyes and the redox couples originally optimized for TiO2.We evaluate the performance of solar cells based on ZnO nanomaterial prepared by microwave-assisted solvothermal synthesis, using three fully organic benzothiadiazole-based dyes YKP-88, YKP-137, and MG-207, and alternative electrolyte solutions with the I−/I3−, Co(bpy)32+/3+, and Cu(dmp)21+/2+ redox couples.The best cell performance is achieved for the dye−redox couple combination YKP-88 and Co(bpy)32+/3+, reaching an average −−efficiency of 4.7% and 5.0% for the best cell, compared to 3.7% and 3.9% for the I /I3 couple with the same dye. Electrical impedance spectroscopy highlights the influence of dye and redox couple chemistry on the balance of recombination and regeneration kinetics. Combined with the effects of the interaction of the redox couple with the ZnO surface, these aspects are shown to determine the solar cell performance. Minimodules based on the best systems in both parallel and series configurations reach 1.5% efficiency for an area of 23.8 cm2.
PB American Chemical Society
YR 2022
FD 2022-11-08
LK http://hdl.handle.net/10433/15697
UL http://hdl.handle.net/10433/15697
LA en
NO ACS Applied Energy Materials, Vol. 5, p. 14092-14106.
NO Área de Química Física
DS RIO
RD May 22, 2026