RT Journal Article T1 Mechanochemical ZIF-9 formation: in situ analysis and photocatalytic enhancement evaluation A1 Rodríguez Sánchez, Noelia A1 Prinz, Carsten A1 Bienert, Ralf A1 Ballesteros, María de la Menta A1 Ruiz-Salvador, A. Rabdel A1 Bhattacharya, Biswajit A1 Emmerling, Franziska K1 Mechanochemical synthesis K1 Solvothermal synthesis K1 MOF K1 Photocatalysis AB Efficient treatment of persistent pollutants in wastewater is crucial for sustainable water management and environmental protection. This study addresses this challenge by investigating the mechanochemical synthesis and photocatalytic performance of ZIF-9, a cobalt-based zeolitic imidazolate framework. Using synchrotron-based powder X-ray diffraction, we provide real-time insights into the formation dynamics of ZIF-9 during mechanosynthesis. Our results show that mechanochemically synthesised ZIF-9 exhibits superior photocatalytic activity compared to its solvothermally prepared counterpart, achieving a 2-fold increase in methylene blue degradation rate. This research not only advances our understanding of the synthesis and properties of ZIF-9, but also demonstrates the potential of mechanochemical approaches in the development of high-performance, sustainably produced materials for water treatment and other environmental applications. PB Royal Society of Chemistry YR 2024 FD 2024-11-19 LK https://hdl.handle.net/10433/23450 UL https://hdl.handle.net/10433/23450 LA en NO RSC Mechanochemistry, 2025, 2, p.116-126 NO Nombre del congreso: Interfaces 2024. Make and MeasureCiudad de celebración: BerlínAutores/as (p. o. de firma): Noelia Rodríguez-Sánchez ;Menta Ballesteros Martín ;A. Rabdel Ruiz ;Biswajit Bhattacharya ;Franziska EmmerlingFecha de celebración: 2024País de celebración: AlemaniaEntidad organizadora: Universidad Humboldt de BerlínTítulo del trabajo: Mechanochemical synthesis of MOF: photocatalytic activity comparison NO Departamento de Biología Molecular e Ingeniería Bioquímica DS RIO RD May 9, 2026