RT Journal Article T1 Coagulation–Flocculation as an alternative way to reduce the toxicity of the black liquor from the paper industry: Thermal valorization of the solid biomass recovered A1 Domínguez-Robles, Juan A1 Palenzuela-Ruiz, María Valle A1 Sánchez, Rafael A1 Mauricio, Javier A1 Espinosa, Eduardo A1 Rosal Raya, Antonio A1 Rodríguez, Alejandro K1 Pulp mill sludge K1 Acidifcation K1 Calorifc potential K1 Biorefnery K1 Wastewater treatment AB Pulp and paper mills generate a huge amount of wastewater and some of them, especially non-wood paper mills, do not possess recovery systems. In this research work, the effectiveness of coagulation–flocculation using poly (ethylene oxide), poly aluminium chloride and poly (dimethyl diallyl ammonium chloride) for the treatment of a black liquor obtained from a pulp mill (with wheat straw as the raw material) is reported. Furthermore, the calorific potential of the solid fraction generated after these treatments was investigated with the aim of enhancing this residue. Chemical oxygen demand (COD), turbidity and total solids (TS) were determined in the supernatants obtained from the different coagulation–flocculation processes. The treatment with poly (ethylene oxide) at pH 2.0 achieved the maximum reduction of TS (66%), COD (75%) and Turbidity (95%) in the black liquor and the precipitated solid fraction with the highest calorific value (19.9 MJ/kg). PB Springer YR 2019 FD 2019-08-14 LK https://hdl.handle.net/10433/22108 UL https://hdl.handle.net/10433/22108 LA en NO Domínguez-Robles, J., Palenzuela, M.V., Sánchez, R. et al. Coagulation–Flocculation as an Alternative Way to Reduce the Toxicity of the Black Liquor from the Paper Industry: Thermal Valorization of the Solid Biomass Recovered. Waste Biomass Valor 11, 4731–4742 (2020). https://doi.org/10.1007/s12649-019-00795-7 NO The authors wish to acknowledge BASF Corporation for providing us with different coagulant samples to use in this study. The authors would also like to thank Ministry of Economy & Competitiveness of Spain (Project CTQ2013-46804-C2-2R), University of Córdoba (RNM 2323) and University Pablo de Olavide (PPI 1401) and, finally, we would like to thank MatchBetter Translations, namely, Carmen Torrella, for reviewing and translating our papers.CTQ2013-46804-C2-2RPPI 1401 UPO NO Universidad Pablo de Olavide. Departamento de Biología Molecular e Ingeniería Bioquímica DS RIO RD May 10, 2026