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Enantioselective Adsorption of Ibuprofen and Lysine in Metal-Organic Frameworks

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URI: https://hdl.handle.net/10433/25796
DOI: 10.1039/c4cc03745f

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2014

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Gómez-Álvarez, Paula
Merklinga, Patrick J.
Vlugtb, Thijs J. H.
van Erpc, Titus
Dubbeldamd, David

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This study reveals the efficient enantiomeric separation of bioactive molecules in the liquid phase. Chiral structure HMOF-1 separates racemicmixtures whereas heteroselectivity is observed for scalemic mixtures of ibuprofen using non-chiral MIL-47 and MIL-53. Lysine enantiomers are only separated by HMOF-1. These separations are controlled by the tight confinement of the molecules.

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info:eu-repo/grantAgreement/MICINN//CTQ2010-16077/ES/SIMULACION MOLECULAR EN MATERIALES POROSOS CRISTALINOS COMO HERRAMIENTA PARA OPTIMIZAR PROCESOS DE INTERES TECNOLOGICO Y MEDIOAMBIENTAL/

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Spanish Government: CTQ2010-16077 European Research Council (ERC): ERC2011-StG-279520-RASPA

Keywords

Enantioselective adsorption
Ibuprofen

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Chem. Commun., 2014,50, 10849-10852

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